Synthesis and Crystal Structure of the Tetranuclear Copper(I) Complex[Cu_4I_4(MPTQ)_2] with a N, S, N'-Tridentate Ligand(MPTQ=8-((2-Pyridylmethyl)thio)quinoline)

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著者

    • SU Cheng-Yong
    • Institute of Physical Chemistry, School of Chemistry and Chemical Engineering, Zhongshan University
    • KANG Bei-Sheng
    • Institute of Physical Chemistry, School of Chemistry and Chemical Engineering, Zhongshan University
    • SUN Jie
    • Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences

抄録

Copper(I) iodide reacts with 8-((2-pyridylmethyl)thio)quinoline (MPTQ) to give the tetranuclear cluster complex [Cu<SUB>4</SUB>I<SUB>4</SUB>(MPTQ)<SUB>2</SUB>] which has been structurally characterized, showing that the Cu<SUB>4</SUB>I<SUB>4</SUB> core exists in a distorted chair-like structure with four copper atoms forming parallelogram which is bridged by iodine atoms on each short sides, by S, N-MPTQ on each long sides and with two additional iodine atoms face-bridging sets of three copper atoms on opposite sides of the parallelogram.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1997(8), 821-822, 1997-08 

    The Chemical Society of Japan

参考文献:  16件

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各種コード

  • NII論文ID(NAID)
    10002614307
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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