On the Basicity of Ozone

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  • Laurence Mariey
    Laboratoire Catalyse et Spectrochimie, UMR CNRS 6506, ISMRA-Université14050 Caen Cedex , France
  • Jean Lamotte
    Laboratoire Catalyse et Spectrochimie, UMR CNRS 6506, ISMRA-Université14050 Caen Cedex , France
  • Philip Hoggan
    Laboratoire Catalyse et Spectrochimie, UMR CNRS 6506, ISMRA-Université14050 Caen Cedex , France
  • Jean-Claude Lavalley
    Laboratoire Catalyse et Spectrochimie, UMR CNRS 6506, ISMRA-Université14050 Caen Cedex , France
  • Kirill Boulanine
    Institute of Physics, St. Petersburg UniversitySt. Petersburg 198904 , Russia
  • Alexei Tsyganenko
    Institute of Physics, St. Petersburg UniversitySt. Petersburg 198904 , Russia

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Comparison of IR spectra of species formed from adsorption of different bases on the acidic OH groups of zeolites (HY, MFI) indicates that O3 basicity is close to that of CO. Calculations confirm such a result ; in particular they involve that the terminal oxygen atoms of ozone are the basic centers.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 26 (8), 835-836, 1997-08-01

    Oxford University Press (OUP)

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