Hydration of Olefins in Excess Water Catalyzed by an Insoluble Cesium Hydrogen Salt of Dodecatungstophosphoric Acid

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著者

    • OKUHARA Toshio
    • Graduate School of Environmental Earth Science, Hokkaido University
    • KIMURA Mutsuko
    • Graduate School of Environmental Earth Science, Hokkaido University
    • NAKATO Teruyuki
    • Graduate School of Environmental Earth Science, Hokkaido University

抄録

A solid acid, Cs<SUB>2.5</SUB>H<SUB>0.5</SUB>PW<SUB>12</SUB>O<SUB>40</SUB>, efficiently catalyzed hydration of 2,3-dimethylbut-2-ene in excess water at 343 K, while typical oxide-based catalysts such as Nb<SUB>2</SUB>O<SUB>5</SUB>, SiO<SUB>2</SUB>-Al<SUB>2</SUB>O<SUB>3</SUB>, TiO<SUB>2</SUB>-SiO<SUB>2</SUB>, and SO<SUB>4</SUB><SUP>2−</SUP>/ZrO<SUB>2</SUB> were almost inactive. The activity (per unit weight) of Cs<SUB>2.5</SUB>H<SUB>0.5</SUB>PW<SUB>12</SUB>O<SUB>40</SUB> was found to be higher than those of liquid acids like H<SUB>3</SUB>PW<SUB>12</SUB>O<SUB>40</SUB> and H<SUB>2</SUB>SO<SUB>4</SUB>, and of a commercial solid acid, H-ZSM-5, for hydration of cyclohexene.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(8), 839-840, 1997-08

    The Chemical Society of Japan

参考文献:  17件中 1-17件 を表示

  • <no title>

    CUSUMANO J. A. and SCHELDON R.

    Chemtech 1992, 1991, 482,566

    被引用文献1件

  • <no title>

    NAMBA S.

    J. Catal. 72, 16, 1981

    被引用文献6件

  • <no title>

    FAJURA F.

    J. Catal. 89, 60, 1984

    被引用文献1件

  • <no title>

    HANAOKA T.

    Catal. Today 8, 123, 1990

    被引用文献1件

  • <no title>

    IZUMI Y.

    Chem. Lett. 1993, 825

    被引用文献1件

  • <no title>

    IZUMI Y.

    Microporous Mater. 5, 255, 1995

    被引用文献4件

  • <no title>

    IZUMI Y.

    Catal. Today 33, 371, 1997

    被引用文献2件

  • <no title>

    OKUHARA T.

    Appl. Catal. A

    被引用文献1件

  • <no title>

    SEGAWA K.

    Proc. 9th Intern. Zeolite Conf. 255, 1993

    被引用文献1件

  • <no title>

    ISHIDA H.

    Petrotech 19, 1030, 1996

    被引用文献1件

  • <no title>

    KONO M.

    Nippon Kagaku Kaishi 1989, 521

    被引用文献2件

  • <no title>

    OKUHARA T.

    J. Mol. Catal. 74, 247, 1992

    被引用文献13件

  • <no title>

    ARATA K.

    Advan. Catal. 37, 165, 1990

    被引用文献2件

  • <no title>

    ITOH M.

    J. Catal. 35, 225, 1974

    被引用文献2件

  • <no title>

    IZUMI Y.

    Proc. Climax 4th Intern. Conf. on the Chemistry and Use of Mo 302, 1982

    被引用文献1件

  • <no title>

    OKUHARA T.

    Advan. Catal. 41, 113, 1995

    被引用文献2件

  • <no title>

    OKUHARA T.

    Stud. Surf. Sci. Catal. 101, 581, 1996

    被引用文献4件

各種コード

  • NII論文ID(NAID)
    10002614439
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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