Stereoselective Synthesis of the LM Ring Moiety of Ciguatoxin : Reagent Control of Asymmetric Dihydroxylation
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Stereoselective synthesis of the LM ring moiety of ciguatoxin was achieved from (<I>R</I>)-(<I>E</I>)-1-benzyloxy-2-hydroxy-3-pentene <I>via</I> Ireland-Claisen rearrangement, iodolactonization, and reagent-controlled asymmetric dihydroxylation.
- Chemistry Letters
Chemistry Letters 1997(9), 845-846, 1997-09
The Chemical Society of Japan