Synthesis of Bis(2, 6-dimesityl-4methylphenyl)phosphaarsene and EPR of its Radical Anion

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著者

    • TSUJI Kyoko
    • Department of Chemistry, Graduate School of Science, Tohoku University
    • FUJII Yuuichi
    • Department of Chemistry, Graduate School of Science, Tohoku University
    • SASAKI Shigeru
    • Department of Chemistry, Graduate School of Science, Tohoku University

抄録

Novel bis(2,6-dimesityl-4-methylphenyl)phosphaarsene was synthesized by the coupling reaction of 2,6-dimesityl-4-methylphenylphosphine with dichloro(2,6-dimesityl-4-methylphenyl)arsine in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene and isolated as stable crystals. The radical anion generated by the sodium metal reduction of the phosphaarsene was investigated by X-band EPR.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1997(9), 855-856, 1997-09 

    The Chemical Society of Japan

参考文献:  19件

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各種コード

  • NII論文ID(NAID)
    10002614562
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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