Hydrogen Abstraction From Unactivated Hydrocarbons Using a Photochemically Excited Isoindoline Nitroxide

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著者

    • CHAND Ugesh
    • CIDC, School of Physical Sciences, Queensland University of Technology

抄録

The photochemically excited nitroxide, 1,1,3,3-tetramethylisoindolin-2-yloxyl (<B>1*</B>), abstracts primary, secondary or tertiary hydrogens from unactivated hydrocarbons including cyclohexane, isobutane and <I>n</I>-butane. The resultant carbon-centred radicals are rapidly and efficiently trapped by ground state nitroxide. Hydrogen abstraction from methane may also occur, but is masked by secondary photochemical reactions.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(9), 857-858, 1997-09

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002614582
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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