Hydrogen Abstraction From Unactivated Hydrocarbons Using a Photochemically Excited Isoindoline Nitroxide

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  • Steven E Bottle
    CIDC, School of Physical Sciences, Queensland University of TechnologyBrisbane Qld 4001 , Australia
  • Ugesh Chand
    CIDC, School of Physical Sciences, Queensland University of TechnologyBrisbane Qld 4001 , Australia
  • Aaron S Micallef
    CIDC, School of Physical Sciences, Queensland University of TechnologyBrisbane Qld 4001 , Australia

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Abstract

<jats:title>Abstract</jats:title> <jats:p>The photochemically excited nitroxide, 1,1,3,3-tetramethylisoindolin-2-yloxyl (1*), abstracts primary, secondary or tertiary hydrogens from unactivated hydrocarbons including cyclohexane, isobutane and n-butane. The resultant carbon-centred radicals are rapidly and efficiently trapped by ground state nitroxide. Hydrogen abstraction from methane may also occur, but is masked by secondary photochemical reactions.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 26 (9), 857-858, 1997-09-01

    Oxford University Press (OUP)

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