Formation of C_<60> Radical Cation in Iron(III)-Exchanged Zeolite Y

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著者

    • URANO Tsutomu
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • TANAKA Keiko
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University

抄録

When C<SUB>60</SUB> is introduced into the Fe<SUP>3+</SUP>-exchanged zeolite Y sample, an intense ESR signal at <I>g</I> = 2.0027 is observed. The ESR signal is due to the formation of C<SUB>60</SUB> radical cation (C<SUB>60</SUB><SUP>•+</SUP>), since the signal intensity increases with an increase in the amount of Fe<SUP>3+</SUP> loaded in the zeolite. Addition of perylene into the C<SUB>60</SUB><SUP>•+</SUP>-zeolite system results in electron transfer from perylene to C<SUB>60</SUB><SUP>•+</SUP> to produce perylene radical cation accompanied by the disappearance of C<SUB>60</SUB><SUP>•+</SUP>.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(9), 875-876, 1997-09

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002614687
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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