Synthesis of Microporous Aluminum Methylphosphonate AlMepO-α by Steam-Induced Topotactic Transformation of AlMepO-β
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Steaming treatment of AlMepO–β at 500 °C induces transformation into AlMepO–α. This procedure easily gives pure AlMepO–α with a large adsorption capacity. A topotactic transformation mechanism through coordination of water molecules at an aluminum site is proposed from comparison of both the framework structures.
- Chemistry Letters
Chemistry Letters 1997(9), 879-880, 1997-09
The Chemical Society of Japan