Synthesis of Microporous Aluminum Methylphosphonate AlMepO-<i>α</i> by Steam-Induced Topotactic Transformation of AlMepO-<i>β</i>

  • Kazuyuki Maeda
    National Institute of Materials and Chemical ResearchHigashi, Tsukuba, Ibaraki
  • Akitsugu Sasaki
    Faculty of Science and Technology, Science University of TokyoYamazaki, Noda, Chiba
  • Kunihiro Watanabe
    Faculty of Science and Technology, Science University of TokyoYamazaki, Noda, Chiba
  • Yoshimichi Kiyozumi
    National Institute of Materials and Chemical ResearchHigashi, Tsukuba, Ibaraki
  • Fujio Mizukami
    National Institute of Materials and Chemical ResearchHigashi, Tsukuba, Ibaraki

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<jats:title>Abstract</jats:title> <jats:p>Steaming treatment of AlMepO–β at 500 °C induces transformation into AlMepO–α. This procedure easily gives pure AlMepO–α with a large adsorption capacity. A topotactic transformation mechanism through coordination of water molecules at an aluminum site is proposed from comparison of both the framework structures.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 26 (9), 879-880, 1997-09-01

    Oxford University Press (OUP)

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