Synthesis and Structure of a Trinuclear Rhenium Cluster Complex [PEt3H][Re3(<i>μ</i>3-S)(<i>μ</i>-S)3Cl6(PEt3)3]

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  • Naofumi Miyake
    Department of Chemistry, School of Science, The University of TokyoHongo, Tokyo
  • Hideo Imoto
    Department of Chemistry, School of Science, The University of TokyoHongo, Tokyo
  • Taro Saito
    Department of Chemistry, School of Science, The University of TokyoHongo, Tokyo

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<jats:title>Abstract</jats:title> <jats:p>Reaction of [Re3(μ3-S)(μ-S2)3Cl6]Cl with triethylphosphine in benzene formed [PEt3H][Re3(μ3-S)(μ-S)3Cl6(PEt3)3]. The triangular cluster has eight metal cluster electrons and the cluster core resembles that of [Mo3(μ3-S)(μ-S)3Cl4L5] cluster complexes.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 26 (9), 913-914, 1997-09-01

    Oxford University Press (OUP)

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