Synthesis of α, β-Unsaturated Carboxylic Acids by Nickel(II)-Catalyzed Electrochemical Carboxylation of Vinyl Bromides

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著者

    • KAMEKAWA Hisato
    • Division of Molecular Chemistry, Graduate School of Engineering, Hokkaido University
    • KUDOH Hiroki
    • Division of Molecular Chemistry, Graduate School of Engineering, Hokkaido University
    • SENBOKU Hisanori
    • Division of Molecular Chemistry, Graduate School of Engineering, Hokkaido University
    • TOKUDA Masao
    • Division of Molecular Chemistry, Graduate School of Engineering, Hokkaido University

抄録

Electrochemical carboxylation of alkyl-substituted vinyl bromides (<B>1a</B>-<B>1g</B>) in the presence of 20 mol% of NiBr<SUB>2</SUB>•bpy under an atmospheric pressure of carbon dioxide with a platinum cathode and a magnesium anode gave the corresponding α,β-unsaturated carboxylic acids (<B>2a</B>-<B>2g</B>) in yields of 53-82%.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(9), 917-918, 1997-09

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002614973
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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