Synthesis, Structure, and Electrochemical Properties of New "Unsymmetrical" Metal Dithiolate Complexes

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New "unsymmetrical" (mixed ligand) metal dithiolate complexes, expected as components of molecular conductors, have been obtained by a ligand-exchange reaction in refluxing acetone, followed by isolation with a preparative HPLC (ODP; acetonitrile-H<SUB>2</SUB>O). Their electrochemical data suggest that the acceptor (donor) ability and the on-site Coulomb energy for the "unsymmetrical" complexes can be tuned by a combination of ligands.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(9), 921-922, 1997-09

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002615018
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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