Synthesis and Characterization of Calcium Endohedral Fullerenes

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The calcium endohedral fullerenes were synthesized by vaporizing the graphite anode filled with CaC<SUB>2</SUB> grains with DC arc, extracted by CS<SUB>2</SUB>, and characterized by field desorption mass spectra. It is found that in the extract most fullerenes between C<SUB>58</SUB> and C<SUB>100</SUB> encapsulated one calcium atom and some trapped two calcium atoms inside. The results show that filling the graphite anode with CaC<SUB>2</SUB> grains is more favorable to the formation of calcium endohedral fullerenes than filling with other materials.

収録刊行物

  • Chemistry letters  

    Chemistry letters 1997(9), 937-938, 1997-09 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002615124
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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