Chiral Recognition in Disproportionation of Monoradical Cation of Optically Active Bisviologen in an Aqueous Solution

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著者

    • ABE Kaya
    • Department of Chemistry, Faculty of Science, Nara Women's University
    • MATSUOKA Maki
    • Department of Chemistry, Faculty of Science, Nara Women's University

抄録

Optically active bisviologens, containing 1-(1-naphthyl)-, 1-phenyl-, and 1-cyclohexylethylamine, were synthesized. Disproportionation of monoradical trications produced by one-electron reduction occurred more easily in the (<I>S</I>,<I>R</I>)-isomers than in the (<I>S</I>,<I>S</I>)- and (<I>R</I>,<I>R</I>)-ones. The disproportionation is controlled by steric bulk of the chiral substituents in <I>intra</I>molecular association between two viologen radical units of diradical dications.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(9), 941-942, 1997-09

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002615148
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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