Asymmetric Transfer Hydrogenation Catalyzed by Diamine - Iridium(I)Complexes

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著者

    • NOMURA Kenji
    • Department of Applied Chemistry, Aichi Institute of Technology
    • HASHIGUCHI Shohei
    • ERATO Molecular Catalysis Project, Research Development Corporation of Japan
    • NOYORI Ryoji
    • ERATO Molecular Catalysis Project, Research Development Corporation of Japan
    • IZAWA Yasuji
    • Department of Applied Chemistry, Aichi Institute of Technology

抄録

Asymmetric transfer hydrogenation of a range of aromatic ketones in 2-propanol was carried out by using the iridium(I) complexes, prepared from [IrCl(cod)]<SUB>2</SUB> and a variety of chiral diamine ligands derived from α-amino acids. Good catalytic activity and enantioselectivity were observed in the presence of KOH at room temperature.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(9), 957-958, 1997-09

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002615247
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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