An Efficient Method for Catalytic and Stereoselective Synthesis of 2-Deoxy-<i>α</i>-<scp>d</scp>-glucopyranosides from 3,4,6,-Tri-<i>O</i>-benzyl-2-deoxy-<scp>d</scp>-glucopyranose and Several Alcoholic Nucleophiles

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  • Kazuya Takeuchi
    Department of Applied Chemistry, Faculty of Science, Science University of Tokyo
  • Satoshi Higuchi
    Department of Applied Chemistry, Faculty of Science, Science University of Tokyo
  • Teruaki Mukaiyama
    Department of Applied Chemistry, Faculty of Science, Science University of Tokyo

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<jats:title>Abstract</jats:title> <jats:p>Several 2-deoxy-α-d-glucopyranosides are stereoselectively synthesized in high yields by glycosylation of various alcoholic nucleophiles with 3,4,6-tri-O-benzyl-2-deoxy-glucopyranose using a catalytic amount of trityl tetrakis(pentafluorophenyl)borate.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 26 (10), 969-970, 1997-10-01

    Oxford University Press (OUP)

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