Hydrogen Abstraction from Transition Metal Hydrides by Gold Alkoxides Giving Gold-Containing Heterodinuclear Complexes

DOI PDF 参考文献38件
  • Yoko Usui
    Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology
  • Masafumi Hirano
    Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology
  • Atsushi Fukuoka
    Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology
  • Sanshiro Komiya
    Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology

この論文をさがす

抄録

<jats:title>Abstract</jats:title> <jats:p>Gold(I) alkoxides, Au(OR)L (L = PPh3, PCy3; R = CH(CF3)2, CH2CF3, Ph) smoothly abstract a hydrogen from transition metal hydrides (MH = CoH(CO)4, MoHCp(CO)3, WHCp(CO)3, MnH(CO)5, WHCp(CO)2(PPh3)) to give corresponding dinuclear complexes LAu-M with liberation of equimolar amount of ROH. Similar reactions of gold(III) alkoxides, cis-AuMe2-(OR)L also give dinuclear intermediates LMe2Au-M, from which preferential reductive elimination of ethane takes place when M is more electron withdrawing.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 26 (10), 981-982, 1997-10-01

    Oxford University Press (OUP)

参考文献 (38)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ