Generation, Characterization and Some Reactions of 1, 1-Ethylene-1H-azulenium Ion

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著者

    • ODA Mitsunori
    • Department of Applied Chemistry, Faculty of Engineering, Toyama University
    • KAJIOKA Takanori
    • Department of Applied Chemistry, Faculty of Engineering, Toyama University
    • ITOH Shunji
    • Department of Chemistry, Faculty of Science, Tohoku University
    • MORITA Noboru
    • Department of Chemistry, Faculty of Science, Tohoku University
    • MIYATAKE Ryuta
    • Department of Applied Chemistry, Faculty of Engineering, Toyama University
    • KURODA Shigeyasu
    • Department of Applied Chemistry, Faculty of Engineering, Toyama University

抄録

The title carbocation, generated from 1,1-ethylene-1,6-dihydroazulene and trityl tetrafluoroborate in deuterated acetonitrile at −20 °C, was characterized by means of low temperature NMR spectroscopy, and was found to undergo expansion of the cyclopropane ring at elevated temperature and to react with nucleophiles to give the addition products at the cyclopropane methylene carbon.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(10), 1011-1012, 1997-10

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002615706
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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