Integrated Chemical Process. One-Pot Preparation of Acetylenes by Peterson-Sulfone Elimination

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  • Akihiro Orita
    Department of Applied Chemistry, Okayama University of Science
  • Naonori Yoshioka
    Department of Applied Chemistry, Okayama University of Science
  • Junzo Otera
    Department of Applied Chemistry, Okayama University of Science

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Integration of silylation of α-sulfonyl carbanion, addition of the anion of the resulting α-silyl sulfone to aldehyde, Peterson elimination, and sulfone elimination leads to one-pot synthesis of acetylenes.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 26 (10), 1023-1024, 1997-10-01

    Oxford University Press (OUP)

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