Efficient Quenching of the Fluorescence of Aromatic Guests by β-Cyclodextrin-Tethered Viologens <i>via</i> Inclusion Complexation

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<jats:title>Abstract</jats:title> <jats:p>The fluorescence quenching of 3-(2-naphthoxyl)-1-aminopropane (1), 3-(1-naphthoxyl)-1-aminopropane (2), and 3-(2-dibenzofuranoxyl)-1-aminopropane (3) by β-cyclodextrin (β-CD)-bound viologens is much more efficient than that by dimethyl viologen. The binding studies of the guests with β-CD and lifetime measurements of the quenching indicated that this is due to the static quenching in complexes formed by inclusion of the aromatic guests into β-CD moiety of the β-CD- viologens.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 26 (10), 1043-1044, 1997-10-01

    Oxford University Press (OUP)

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