Aerobic Oxidation of Cyclohexane Catalyzed by Fe(III)(5, 10, 15, 20-tetrakis(pentafluorophenyl)porphyrin)Cl in Sub- and Super-Critical Co_2
Aerobic oxidation of cyclohexane to yield cyclohexanol and cyclohexanone in the presence of a Fe-porphyrin catalyst bearing meso-pentafluorophenyl group and acetaldehyde has been efficiently enhanced in pressurized CO<SUB>2</SUB>. The reaction rate takes a maximum value in the neighborhood of critical pressure.
- Chemistry letters
Chemistry letters 1997(10), 1045-1046, 1997-10
The Chemical Society of Japan