On the Origin of cis-Effect in 1, 2-Difluoroethene

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著者

    • YAMAMOTO Takashi
    • Department of Life and Environmental Sciences, Graduate School of Arts and Sciences, The University of Tokyo
    • TOMODA Shuji
    • Department of Life and Environmental Sciences, Graduate School of Arts and Sciences, The University of Tokyo

抄録

The origin of <I>cis</I>-effect in 1,2-difluoroethene has been identified by quantitative analysis of electron delocalization using natural bond orbital analysis at the HF/6-311++G(3df, 3pd) level. It was concluded that both the delocalization of halogen lone-pair electrons (LP effect) and the antiperiplanar effects (AP effect) between vicinal antiperiplanar bonds are most likely to be the major sources of <I>cis</I>-effect with the latter effect being the more predominant.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(10), 1069-1070, 1997-10

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002616165
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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