Base Promoted Preparation of Alkenylsilanols from Allylsilanes
On treatment of allyl-<I>t</I>-butyldiphenylsilane with <I>t</I>-BuOK and 18-Crown-6 in DMSO at room temperature, isomerization of the olefinic double bond and subsequent substitution of phenyl group with hydroxy group took place smoothly to afford alkenylsilanol derivatives in good yields.
- Chemistry letters
Chemistry letters 1997(10), 1077-1078, 1997-10
The Chemical Society of Japan