Base Promoted Preparation of Alkenylsilanols from Allylsilanes
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On treatment of allyl-<I>t</I>-butyldiphenylsilane with <I>t</I>-BuOK and 18-Crown-6 in DMSO at room temperature, isomerization of the olefinic double bond and subsequent substitution of phenyl group with hydroxy group took place smoothly to afford alkenylsilanol derivatives in good yields.
- Chemistry Letters
Chemistry Letters 1997(10), 1077-1078, 1997-10
The Chemical Society of Japan