Open Dimer Participation in Chelation Controlled Addition of Methyllithium Dimer to α-andβ-Alkoxy Aldehydes

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The chelation controlled additions of a MeLi dimer to alkoxy carbonyl compounds occur through an open dimer cluster, in which only one lithium atom participates in the chelate formation and the other acts as an anchor of the methyl nucleophile to be delivered to the carbonyl group. Solvation of a lithium atom with a water molecule does not change much the structure of the transition state.

収録刊行物

  • Chemistry letters

    Chemistry letters 1997(10), 1079-1080, 1997-10

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002616252
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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