アルミニウム陽極酸化皮膜への電析金属の二次イオン質量分析 Secondary ion mass spectrometry of the electrodeposition metals in anodizing films of aluminum

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著者

    • 水本 一 MIZUMOTO Hajime
    • 近畿大学理工学部応用化学科 Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University
    • 野口 駿雄 NOGUCHI Hayao
    • 近畿大学理工学部応用化学科 Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University

抄録

Standard sample is necessary for determination on surface analysis, and particularly it is difficult to make a standard sample for secondary ion mass spectrometry (SIMS). A sample turned ion implantation into is used for a standard sample of quantitative analysis with SIMS, but it is neither simple nor easy to make a standard sample for the analysis of various kinds of samples. The first electrolysis was done with sulfate (H<sub>2</sub>SO<sub>4</sub>) bath and trisodium phosphate (Na<sub>3</sub>PO<sub>4</sub>) bath, and second electrolysis of tin and nickel was done on the films. The trace metals (Sn and Ni) deposited by second electrolysis was determined by graphite furnace atomic absorption spectrometry (GFAAS), and it was investigated to make the standard sample for the analysis of electrolytic pigmentation coatings on SIMS. The relative sensitivity factor (RSF) was calculated from the film density measured with GFAAS. RSF of <sup>120</sup>Sn was 4.63 × 10<sup>14</sup> in coating formed with H<sub>2</sub>SO<sub>4</sub> bath, and RSF of <sup>120</sup>Sn was 3.142 × 10<sup>14</sup> in coating formed with Na<sub>3</sub>PO<sub>4</sub> bath. As the result of the depth profiles by SIMS, the deposition behavior of the metal was different by the kind of first electrolysis baths; the metal deposited along pore wall in H<sub>2</sub>SO<sub>4</sub> bath coating, and the metal accumulated in pore bottom in Na<sub>3</sub>PO<sub>4</sub> bath coating. The distribution of concentration and the deposition behavior of metal was elucidated with SIMS.

収録刊行物

  • 軽金属  

    軽金属 48(8), 390-394, 1998-08 

    The Japan Institute of Light Metals

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各種コード

  • NII論文ID(NAID)
    10002665078
  • NII書誌ID(NCID)
    AN00069773
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    04515994
  • NDL 記事登録ID
    4652057
  • NDL 雑誌分類
    ZP41(科学技術--金属工学・鉱山工学)
  • NDL 請求記号
    Z17-284
  • データ提供元
    CJP書誌  CJP引用  NDL  J-STAGE 
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