Measurement and Correlation of Solubility of Limonene and Linalool in High Pressure Carbon Dioxide.

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  • リモネン,リナロールの高圧二酸化炭素への溶解度測定と相関
  • リモネン リナロール ノ コウアツ 2サンカ タンソ エ ノ ヨウカイド ソク

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Abstract

In order to carry out the deterpenation of orange oil using carbon dioxide extraction under high pressure, the solubilities of constituents were examined experimentally. Limonene and linalool were selected as the major component and a flavor component, respectively. Solubilities of each component in high pressure carbon dioxide were measured by use of a high pressure cell with glass windows at 313 K and 333 K and from 1 MPa to the near critical point. All isothermal solubilities had minima against pressure and they increased along with temperature. Solubility data have been correlated based not only on the regular solution theory but the SRK equation of state. The solubilities of limonene have been correlated well by the regular solution theory, and those of linalool have been represented fairly accurately by the SRK equation.

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