石英ガラス製反応管内での酸素によるNiCl_2熱分解反応速度 Decompositrion Rate of NiCl_2 with Oxygen in Quartz Glass Tube
Decomposition rate of NiCl2 with oxygen was measured in quartz glass tube. Under the experimental condition (reaction temperature : 973-1073 K, NiCl<SUB>2</SUB> partial pressure : 2.46 7.43 × 10<SUP>-5</SUP> MPa, O<SUB>2</SUB> partial pressure : 1.36.3×10<SUP>-3</SUP> MPa), it was found that the decomposition rate was strongly affected by the surface area in the reactor and the reaction rate was described the product of the reaction rate constant k, the surface area in the reactor S, the 1.3 th power of NiCl<SUB>2</SUB> partial pressure and the 1.2 th power of oxygen partial pressure. Also, the activation energy of this reaction was obtained 80.1 kJ/mol.
化学工学論文集 22(1), 201-205, 1996-01-20
The Society of Chemical Engineers, Japan