Effects of Pressure and Ca2+ on the Fe-Mg Partitioning between Olivine and Clinopyroxene.

  • KAWASAKI Tashisuke
    Division of Earth Sciences, Department of Biosphere and Geosphere Sciences, Faculty of Science, Ehime University

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  • Effects of Pressure and Ca2 + on the Fe

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The exchange reaction of Fe2+ and Mg2+ between olivine and clinopyroxene has been experimentally determined at 1150°C, and at pressures 1 and 1. 5 GPa in the Ca-poor and Ca-enriched systems, the bulk ratio Fe/ (Fe+Mg) which was fixed as about 0. 5. The CaO contents of olivine and clinopyroxene seriously affect on the Fe-Mg partition coefficient KD [= (XCpxMg XOlFe) / (XCpxFe XOlMg) ], which increases with increasing XOlCa. The KD was found as 1. 50 at 1 GPa for the assemblage of olivine (XOlCa = 0. 006) and subcalcic clinopyroxene (XCpxCa = 0. 2898) ; 2. 90 at 1. 5 GPa for the assemblage of diopside-hedenbergite clinopyroxene and olivine (XOlCa = 0. 1048), in contrast to 3. 00 at 1 GPa for the assemblage of diopside-hedenbergite clinopyroxene, olivine with XOlCa = 0. 1464 and ferroan monticellite. On the other hand, the distribution coefficient KD was found to be insensitive to pressure comparing with the previous data. The olivine-ferroan monticellite solvus becomes narrow with increasing pressure, but this pressure effect on the solvus is very small.

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