Hydrogen Bonding in M(OD)2 Compounds Under Pressure.

DOI Web Site 被引用文献3件 参考文献69件
  • Parise John B.
    CHiPR and Department of Geosciences, State University of New York
  • Cox Hugh
    CHiPR and Department of Geosciences, State University of New York
  • Kagi Hiroyuki
    CHiPR and Department of Geosciences, State University of New York
  • Li Rui
    CHiPR and Department of Geosciences, State University of New York
  • Marshall William
    Department of Physics and Astronomy, The University of Edinburgh
  • Loveday John S.
    Department of Physics and Astronomy, The University of Edinburgh
  • Klotz Stefen
    Physique des Milieux Condensés (CNRS URA 782) Universiteé P et M Curie

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  • Hydrogen Bonding in M OD 2 Compounds Un

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The structures of the deuterated hydroxides (M (OD) 2; M=Mg, Ca, Mn, Ni, Co) have been refined using the Rietveld method and neutron powder diffraction data collected at high pressure. There is no statistically significant increase in the O-D interatomic distance at increased pressure while the hydrogen bonding interaction D. . . O increases as this distance decreases and the O-D. . . O angle increases. The intramolecular O-D bond valences, determined indirectly from the intermolecular D. . . O distances, decrease steadily for all materials as pressure is increased.

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