X-ray Diffraction Study of Zn3(PO4)24H2O and Zn/Ca Phosphates at High Pressure and Temperature.

  • Olsen J. Staun
    Niels Bohr Institute, Oersted Laboratory, University of Copenhagen
  • Steenstrup S.
    Niels Bohr Institute, Oersted Laboratory, University of Copenhagen
  • Gerward L.
    Department of Physics, Technical University of Denmark
  • Olesen P. T.
    Department of Chemistry, Technical University of Denmark
  • Stenberg T.
    Department of Chemistry, Technical University of Denmark

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  • X-ray Diffraction Study of Zn3 PO4 24H2

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Abstract

High-pressure and high-temperature experiments on Zn3 (PO4) 4H2O (Hopeite) and Zn/Ca phosphates have been carried out using the MAX 80 high pressure equipment. Fitting of Murnaghan's equation of state to the experimental data has been used to obtain the bulk modulus and its pressure derivative for Hopeite. Recrystallization of Zn/Ca phosphates at increasing temperature has been demonstrated.

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