High-Pressure Structural Studies of Hydroxides.
-
- Loveday J. S.
- Department of Physics and Astronomy, The University of Edinburgh
-
- Marshall W. G.
- Department of Physics and Astronomy, The University of Edinburgh
-
- Nelmes R. J.
- Department of Physics and Astronomy, The University of Edinburgh
-
- Besson J. M.
- Physique des Milieux Condensés Université P. et M. Curie
-
- Klotz S.
- Physique des Milieux Condensés Université P. et M. Curie
-
- Hamel G.
- Département des Hautes Pressions, Université P. et M. Curie
Bibliographic Information
- Other Title
-
- High-Pressure Structural Studies of Hyd
Search this article
Abstract
Hydrogen bonds involving hydroxyl groups appear to to be significantly different from the H-bonds found in molecular solids. High-pressure structural studies of hydroxides using neutron diffraction provide a means to explore the changes in geometry over a wide range of interatomic separations. The structure of NaOD-V is found to have a complex geometry which appears on the basis of bond-valence-sum calculations to be at most weakly H-bonded. KOD-VI is found not to be structurally related to NaOD-V as previously thought. Studies of ammonia monohydrate have provided the first full determination of the ambient pressure structure and have revealed phase transitions under pressure.
Journal
-
- The Review of High Pressure Science and Technology
-
The Review of High Pressure Science and Technology 7 376-378, 1998
The Japan Society of High Pressure Science and Technology
- Tweet
Details
-
- CRID
- 1390282679358281216
-
- NII Article ID
- 10002690190
-
- NII Book ID
- AN10452913
-
- ISSN
- 13481940
- 0917639X
-
- NDL BIB ID
- 4493933
-
- Text Lang
- en
-
- Data Source
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- Abstract License Flag
- Disallowed