Pressure Induced Mode Softening in Ge.

  • Klotz S.
    Physique des Milieux Condensés, Université P&M Curie
  • Besson J. M.
    Physique des Milieux Condensés, Université P&M Curie
  • Braden M.
    Laboratoire Léon Brillouin, CE-Saclay
  • Karch K.
    IFTO, Friedrich-Schiller-Universität

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Abstract

A complete set of transverse acoustic phonon frequencies of Ge has been measured at pressures to 9. 7 GPa by inelastic neutron scattering and studied by ab initio calculations using density functional perturbation theory. The measurements provide for the first time q-dependent Grüneisen parameters for all TA-modes along high symmetry directions. At the X and L points, the pressure dependence of the phonon frequency ω is shown to be that of a classical soft mode with ω2 strictly linear in pressure P.

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