Structural Studies on Solid CCl4 under High Pressure.

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  • Structural Studies on Solid CCl4 under

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Abstract

The pressure-induced phase transformation of CCl4 was studied with an x-ray and a Raman scattering experiments. The transition from the phase III to the phase IV takes place around 2. 3 GPa. The space group of the phase IV is determined to be Pa3. Above 6 GPa, an intramolecular vibrational mode of F2 gradually splitted into three peaks. It suggests a phase transition to a new high pressure phase.

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