Comparative Raman Spectroscopy of Nitromethane-h3, Nitromethane-d3, Nitroethane and Tetranitromethane under High Pressure

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Nitromethane has been studied as a model of energetic aliphatic nitro-compound. The initiation of the decomposition mechanism of nitromethane in the vicinity of the temperature and pressure conditions of explosion has been studied under high static pressure by Raman spectroscopy. The vibrational modes v<SUB>a</SUB> (NO<SUB>2</SUB>) and, in a smaller scale, v<SUB>s</SUB> (NO<SUB>2</SUB>) show a specific behavior at the solid (II) -solid (III) 7. 5 GPa transition (at ambient temperature). The comparison of the Raman spectrum of nitromethane-h<SUB>3</SUB> with new Raman spectroscopic results under pressure of nitromethane-d<SUB>3</SUB>, nitroethane and tetranitromethane allows to characterize a physico-chemical behavior of these compounds in relation with their exploding properties.

収録刊行物

  • 高圧力の科学と技術 = The Review of high pressure science and technology

    高圧力の科学と技術 = The Review of high pressure science and technology 7, 897-899, 1998

    The Japan Society of High Pressure Science and Technology

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各種コード

  • NII論文ID(NAID)
    10002692253
  • NII書誌ID(NCID)
    AN10452913
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    0917639X
  • NDL 記事登録ID
    4494093
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z17-1589
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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