Pressure Effect on Synthesis of TISr2Ca2Cu3Oy and TISr2Ca3Cu4Oy

  • Atou T.
    Institute for materials Research, Tohoku University
  • Ohshima E.
    Institute for materials Research, Tohoku University
  • Kikuchi M.
    Institute for materials Research, Tohoku University
  • Syono Y.
    Institute for materials Research, Tohoku University

書誌事項

タイトル別名
  • Pressure Effect on Synthesis of TlSr2Ca2Cu3Oy and TlSr2Ca3Cu4Oy.
  • Pressure Effect on Synthesis of TISr2Ca

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抄録

Thallium based cupurate superconductors, TlSr2Ca2Cu3Oy and TlSr2Ca3Cu4Oy, were synthesized using a high-pressure technique. Synthesis condition was 2. 5 GPa, 1000°C for 4 hours for TlSr2Ca2Cu3Oy, and 1. 5 GPa, 950°C for 4 hours for TlSr2Ca3Cu4Oy. Lattice parameters were α=3. 823 Å and c=15. 33 Å for TlSr2Ca2Cu3Oy, and α=3. 830 Å and c=18. 49 Å for TlSr2Ca3Cu4Oy. The synthesis pressure and heating time were fairly critical to obtain single phases. Tc was 97 K and 90 K for TISr2Ca2Cu3Oy, and TlSr2Ca3Cu4Oy, respectively.

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