Phase Equilibria in Binary Liquid Crystalline Systems under High Pressure.

  • Tanaka Y.
    Department of Chemical Science and Engineering, Faculty of Engineering Kobe University
  • Hiramatsu Y.
    Department of Chemical Science and Engineering, Faculty of Engineering Kobe University
  • Matsuo S.
    Department of Chemical Science and Engineering, Faculty of Engineering Kobe University

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タイトル別名
  • Phase Equilibria in Binary Liquid Cryst

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The effect of pressure on the crystal-nematic and nematic-isotropic transition temperatures, TCN and TNI, was investigated for MBBA (n- (4-methoxybenzylidene) -4-n- butylaniline), EBBA (n- (4-ethoxybenzylidene) -4-n-butylaniline), and binary mixtures containing these compounds such as (MBBA+EBBA), and (MBBA, EBBA + C6H6, C6H12) at temperatures from 263 to 363 K and pressures up to 30 MPa. The measurements were performed using a high-pressure optical vessel designed for direct visual observation with the aid of a video microscope, and a three-terminal cylindrical capacitor for dielectric study.

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