The Influence of High Pressure in Palladium Catalyzed Coupling Reactions

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抄録

The influence of high pressure (1-10 kbar) in solution on palladium catalyzed coupling reactions is examined bothunder the aspect of reactivity as well as selectivity. We present evidence that pressure can considerably accelerate such reactions as well as dramtically increase the turnover numbers of the catalysts. Moreover, new catalytic reactions become possible by using pressure: we present here our preliminary results on palladium catalyzed acylations of alkenes and the synthesis of trisubstituted alkenes by a new domino process combining the Horner-Wadsworth-Emmons and the Heck reaction.

収録刊行物

  • 高圧力の科学と技術 = The Review of high pressure science and technology  

    高圧力の科学と技術 = The Review of high pressure science and technology 7, 1241-1243, 1998 

    The Japan Society of High Pressure Science and Technology

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各種コード

  • NII論文ID(NAID)
    10002693526
  • NII書誌ID(NCID)
    AN10452913
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    0917639X
  • NDL 記事登録ID
    4494203
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z17-1589
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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