The Influence of High Pressure in Palladium Catalyzed Coupling Reactions.

• Hillers Stephan

  lnstitut für Organische Chemie der Universität Regensburg, Universitätsstr.

• Mengel Anne

  lnstitut für Organische Chemie der Universität Regensburg, Universitätsstr.

• Bodmann Kerstin

  lnstitut für Organische Chemie der Universität Regensburg, Universitätsstr.

• Reiser Oliver

  lnstitut für Organische Chemie der Universität Regensburg, Universitätsstr.

Bibliographic Information

Other Title

• The Influence of High Pressure in Palla

Abstract

The influence of high pressure (1-10 kbar) in solution on palladium catalyzed coupling reactions is examined bothunder the aspect of reactivity as well as selectivity. We present evidence that pressure can considerably accelerate such reactions as well as dramtically increase the turnover numbers of the catalysts. Moreover, new catalytic reactions become possible by using pressure: we present here our preliminary results on palladium catalyzed acylations of alkenes and the synthesis of trisubstituted alkenes by a new domino process combining the Horner-Wadsworth-Emmons and the Heck reaction.

Journal

• The Review of High Pressure Science and Technology

  The Review of High Pressure Science and Technology 7 1241-1243, 1998

  The Japan Society of High Pressure Science and Technology

Keywords

• palladium
• alkenes
• α
• β-unsaturated ketones
• Heck reaction
• Horner-Wadsworth-Emmons reaction

Details

• CRID: 1390001204382209024
• NII Article ID: 10002693526
• NII Book ID: AN10452913
• DOI: 10.4131/jshpreview.7.1241
• ISSN: 13481940
• ISSN: 0917639X
• NDL BIB ID: 4494203
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4494203
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed