Organic Synthesis at High Pressure. Efficient Ring Opening Reaction of Epoxides with Heterocycles

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A selective ring opening reaction of epoxides with a variety of heterocyclic compounds including indoles, pyrroles, pyrazoles, furans, and thiophenes proceeded efficiently under high pressures. For nitrogen heterocycles, the reactionoccurred under essentially uncatalyzed conditions. On the other hand, furan and thiophene required the use of suitable acid catalysts due to their low nucleophilicity. These methods were applied successfully to the design of new heterocyclic chiral ligands and to the synthesis of biologically interesting natural products. The underlying principle responsible for these high-pressure reactions is discussed.

収録刊行物

  • 高圧力の科学と技術 = The Review of high pressure science and technology  

    高圧力の科学と技術 = The Review of high pressure science and technology 7, 1250-1252, 1998 

    The Japan Society of High Pressure Science and Technology

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各種コード

  • NII論文ID(NAID)
    10002693577
  • NII書誌ID(NCID)
    AN10452913
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    0917639X
  • NDL 記事登録ID
    4494205
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z17-1589
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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