Comparative Activation Modes in Organic Chemistry. Pressure vs Hydrophobic Effects

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抄録

The merits of two activation modes in organic synthesis are compared: pressure and physicochemical activation. The latter mode considers hydrophobic effects arising from aggregation of organic molecules in water. Both activation types stimulate the reactivity of addition reactions such as [4+2] cycloadditions, Michael additions and Baylis-Hillman reactions. However, the effect of water is complex and usually not predictable whereas high pressure proves to be an excellent activation mode. Combination of both activation processes can lead to convergent syntheses.

収録刊行物

  • 高圧力の科学と技術 = The Review of high pressure science and technology

    高圧力の科学と技術 = The Review of high pressure science and technology 7, 1268-1270, 1998

    The Japan Society of High Pressure Science and Technology

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各種コード

  • NII論文ID(NAID)
    10002693675
  • NII書誌ID(NCID)
    AN10452913
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    0917639X
  • NDL 記事登録ID
    4494211
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z17-1589
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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