The Stabilization of C_3N_4 : New Development of Such a Material as Macroscopic Sample

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著者

    • BIROT M.
    • Laboratoire de Chimie Organique et Organometallique Universite Bordeaux I
    • DUNOGUES J.
    • Laboratoire de Chimie Organique et Organometallique Universite Bordeaux I

抄録

Materials with high elements (C, B, N. . . ) appear to be a great interest for the future. The most dense forms of these materials are characterized by exceptional physico-chemical properties (diamond, c-BN, β-C<SUB>3</SUB>N<SUB>4</SUB>. . . ). The last material (C<SUB>3</SUB>N<SUB>4</SUB>) issued from "ab-initio" calculations has instigated the development of researches for its preparation mainly as microscopic sample (carbon-nitride thin film deposition). Recently, we have proposed a new approach for the synthesis of the graphitic phase of C<SUB>3</SUB>N<SUB>4</SUB> (g-C<SUB>3</SUB>N<SUB>4</SUB>) based on the solvothermal condensation or organic precursors (as melamine or C<SUB>3</SUB>N<SUB>3</SUB>Cl<SUB>3</SUB>). Using a non-nucleophilic basis as solvent in the pressure-temperature conditions close to 130 MPa and 250°C, the graphitic form of C<SUB>3</SUB>N<SUB>4</SUB> was prepared. The physico-chemical characterizations (XRD, Electron Probe Micro-analysis, SEM, Raman and XPS Spectroscopies) confirm this structure. Such a C<SUB>3</SUB>N<SUB>4</SUB> form appears to be a good precursor for preparing the denser forms.

収録刊行物

  • 高圧力の科学と技術 = The Review of high pressure science and technology  

    高圧力の科学と技術 = The Review of high pressure science and technology 7, 1345-1347, 1998 

    The Japan Society of High Pressure Science and Technology

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各種コード

  • NII論文ID(NAID)
    10002694019
  • NII書誌ID(NCID)
    AN10452913
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    0917639X
  • NDL 記事登録ID
    4494235
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z17-1589
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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