Low Temperature Hydrothermal Synthesis of BaMg1/3Ta2/3O3 Sols and Powders.

  • MacLaren I.
    IRC in Materials for High Performance Applications and School of Metallurgy and Materials, University of Birmingham
  • Ponton C. B.
    IRC in Materials for High Performance Applications and School of Metallurgy and Materials, University of Birmingham

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  • Low Temperature Hydrothermal Synthesis

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Abstract

Perovskite BaMg1/3Ta2/3O3 sol-derived powders have been produced by hydrothermal synthesis at low temperatures of 160°C - 350°C. The particles in these powders tend to be irregular shaped, ultra-fine and magnesium-deficient. Methods have been found for producing near-stoichiometric particles and these have more rounded morphologies and larger sizes. Thus, a clear link has been established between the stoichiometry and morphology of the powder particles which suggests that the particle growth mechanisms under hydrothermal conditions are affected strongly by stoichiometry.

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