Synthesis of Processes for Recovering Metals from Incineration Fly Ash of Municipal Solid Wastes.

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  • Kim Jong-Hwa
    Department of Chemical Engineering, Osaka University College of Engineering, Changwon National University
  • Yang Jong-Gyu
    Department of Chemical Engineering, Osaka University College of Engineering, Changwon National University
  • Kunugita Eiichi
    Department of Chemical Engineering, Osaka University College of Engineering, Changwon National University

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  • 都市ゴミ焼却炉飛灰から金属類を分離するプロセス
  • トシ ゴミ ショウキャクロ ヒカイ カラ キンゾクルイ オ ブンリスル プロセ

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Abstract

The purpose of this study is development of separation processes by which metal elements worth using for raw materials of chemicals (for examples Cd, Cu, Mn, Pb, Zn and so on) are recovered from incineration fly ash of municipal solid wastes.<BR>Candidate Process (D) evolved out of Candidate Process (C), which was synthesized with a computer-aided procedure. The process consists of addition of Na2S to nitric solution as leachate of the fly ash for forming precipitate of sulfides, and consecutive dissolution of sulfides with dil-H2SO4, conc-H2SO4 and HNO3 to separate Mn2+, Zn2+ and Cd2+ from each other and to leave CuS insoluble in the acids. For further purification of metals, Candidate Process (D) was modified into Candidate Process (E), in which solvent extraction of Zn2+ from Mn2+ and Cd2+ fractions with bis (2-ethylhexyl) phosphoric acid (D 2 EHPA), and addition of NH2aq or (NH4) 2CO3 to form [Cu (NH3) 4] 2+ and to leave PbS insoluble were adopted.

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