流れの数値解析と化学装置のモデリング  メタノール,tert‐ブチルアルコール,tert‐ブチルメチルエーテルおよび水を組み合わせた5種の二成分系とメタノールとtert‐ブチルアルコールによるエーテル化反応系の大気圧下における気液平衡データ

書誌事項

タイトル別名
  • Computation Transport Phenomena in Chemical Engineering. Vapor-Liquid Equilibrium Data for Five Binary Systems of Methanol, tert-Butylalcohol, tert-Butylmethylether and Water, and Quaternary Reactive System Producing tert-Butylmethylether from Methanol and tert-Butylalcohol.
  • メタノール tert-ブチルアルコール tert-ブチルメチルエーテル オヨビ

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抄録

At atmospheric pressure, vapor-liquid equilibrium relationships for five binary systems of methanol-tert-butylalcohol, methanol-tert-butylmethylether, tert-butylal-cohol-tert-butylmethylether, water-tert-butylalcohol and water-tert-butylmethyleth-er are observed. The Wilson parameters for the binary systems have been obtained. Comparisons between the Wilson method, The ASOG method and the UNIFAC method are made. Vapor-liquid equilibrium relationships of the quaternary reactive system producing tert-butylmethylether by use of methanol and tert-butylalcohol are also observed, and it is confirmed that the Wilson parameters resulting from the data of binary systems can be used to estimate the vapor-liquid equilibrium data for the quaternary reactive system of methanol-tert-butylalcohol-tert-butylmethylether-water.

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