Studies on the Distortion of the Director Field in Shear Flow for Nematic Solutions of a Rodlike Polymer

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  • Studies on the Distortion of the Direct

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The rheological behavior on shear flow of aligned nematic solutions of rodlik Poly(1,4-phenylene-2,6-enzobisthiazole), PBZT, is discussed. The results show that the initial transient response to the onset of flow reflects the curvature elasticity, with minimal distortion of the director field near the shear surfaces. With increasing strain, the behavior is complicated by rotation of the rodlike chains out of the shear plane, causing, for example, a loss of conoscopic interference figures, and a decrease in the anisotropy of the fluorescence emitted from the first micron thickness near the shear surface. Line-defects appear with continued shear flow.

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