Thermoelectric Properties of Bi-Sb Sintered Alloys Prepared under Unidirectional High Pressure

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  • 一軸超高圧で作製したBi-Sb焼結体の熱電気的特性
  • 1ジク チョウコウアツ デ サクセイシタ Bi Sb ショウケツタイ ノ ネツ

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Abstract

Ultra fine powder of Bi91Sb9 was sintered under unidirectional high pressure. The powder was prepared by the hydrogen plasma-metal reaction method. The sintered alloys have a layered structure of grains oriented perpendicular to the press axis, resulting in the anisotropic thermoelectric properties. The Seebeck coefficient of the sintered alloys increases by applying a magnetic field. The magnetic field variation of the Seebeck coefficient depends on the direction of a magnetic field. This dependence could be explained by the shape effect of grains in the sintered alloys on the thermoelectric transverse-transverse effect. The power factor of the sintered alloys is improved by applying a magnetic field, and its value reachs to 2.8× 10-5W/cmK2 at H=5kOe and T=172K.

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