n型導電性高分子ポリ(p-ピリジルビニレン)を用いた電界発光素子

• 小野田 光宣

  姫路工大

• Macdiarmid Alan G.

  ペンシルバニア大

書誌事項

タイトル別名

• Electroluminescent Devices Using n-Type Conducting Polymers: Poly (p-pyridyl vinylene)
• nガタ ドウデンセイ コウブンシ ポリ p ピリジルビニレン オ モチイタ デ

抄録

A new n-type conducting polymer poly (p-pyridyl vinylene), (PPyV) was synthesized by the C-C cross coupling reaction of 2, 5-dibromopyridine and 1, 2-bis (tributylstannyl) ethylene catalyzed by palladium complex. We have reported investigations of electroluminescence (EL) in PPyV which we have used in a range of single-and double-layer EL devices. EL in the yellow region of the spectrum with a maximum at 585nm was observed from PPyV sandwiched between indium-tin-oxide and Al electrodes. In double-layer device which incorporate a thin film of poly (p-phenylene vinylene), (PPV) as a hole transport layer, yellow-orange emission with 0.08% external quantum efficiency can be achieved. EL originates from the radiative decay of the chromophore singlet polaron exciton created as a result of the recombination of injected charge carriers.

収録刊行物

• 電気学会論文誌．　Ａ

  電気学会論文誌．　Ａ 116 (6), 516-521, 1996

  一般社団法人 電気学会

キーワード

• ポリ(p-ピリジルビニレン)
• 電界発光素子
• 電子状態
• 励起子ポーラロン
• 放射再結合

詳細情報

• CRID: 1390001204599764096
• NII論文ID: 130006839451
• NII論文ID: 10002819703
• NII書誌ID: AN10136312
• DOI: 10.1541/ieejfms1990.116.6_516
• ISSN: 13475533
• ISSN: 03854205
• NDL書誌ID: 3966460
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I3966460
• Web Site: https://www.jstage.jst.go.jp/article/ieejfms1990/116/6/116_6_516/_pdf
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• 抄録ライセンスフラグ: 使用不可