Tetraethoxysilaneを用いたプラズマCVD法における気相分解過程

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タイトル別名
  • Investigation on Dissociation Process in Plasma Enhanced Chemical Vapor Deposition Using Tetraethoxysilane
  • Tetraethoxysilane オ モチイタ プラズマ CVDホウ ニ オ

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抄録

Dissociation in plasma enhanced chemical vapor deposition for SiO2 deposition using Tetraethoxysilane (TEOS) was investigated by means of mass spectrometry. First we showed basic dissociation patterns of TEOS by electron impact. It was shown that the TEOS was dissociated by electron impact at low electron energy below 7eV removing the ethyl group (C2H5). Next we presented dissociation patterns in TEOS/He plasma in order to eliminate the effect of oxidation. Finally dissociation in TEOS/O2 plasma was clarified. As the results, it was found that the oxidation plays a indispensable role for deposition of high quality SiO2 films due to the decrease in high molecular compounds with carbon (C) and hydrogen (H) although the TEOS is highly dissociated by electron impact.

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