Microscopic Structure of Supercritical Water.

• Yamaguchi Toshio

  Department of Chemistry, Faculty of Science, Fukuoka University

Bibliographic Information

Other Title

• 高圧下の水と氷　超臨界水のミクロ構造

Abstract

The microscopic structure of sub-and supercritical water has recently been determined by novel liquid X-ray diffraction using an imaging plate detector and neutron diffraction with isotopic substitution. The X-ray and neutron results are compared with those obtained by Monte Carlo and molecular dynamics computer simulations and Raman and infrared spectroscopy. A recent attempt to obtain the three-dimensional structure of supercritical water by spherical harmonic expansion method is also described Discussion is focused on the degree of hydrogen bonding in supercritical water and its correlation with physicochemical properties.

Journal

• The Review of High Pressure Science and Technology

  The Review of High Pressure Science and Technology 4 (3), 193-200, 1995

  The Japan Society of High Pressure Science and Technology

Keywords

• supercritical water
• X-my and neutron diffraction
• computer simulation
• Raman and infrared spectroscopy
• structure
• hydrogen bonding

Details

• CRID: 1390001204381330432
• NII Article ID: 10002847591
• NII Book ID: AN10452913
• DOI: 10.4131/jshpreview.4.193
• ISSN: 13481940
• ISSN: 0917639X
• Text Lang: ja
• Data Source:
  • JaLC
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed